“Clapeyron represented the Carnot cycle in terms of a Watt indicator diagram; the familiar form that it assumes in the introductory pages of all modern textbooks on thermodynamics. How Clapeyron came to know about the indicator diagram is an intriguing and, at present, unsolved problem in the history of science. The secret was very closely guarded by Boulton and Watt; so well in fact that was not until 1826 that a well-informed engineer like John Farey first saw an indicator diagram being taken in Russia, and in this way learned of the principle.”— Donald Cardwell (1971), From Watt to Clausius (pg. 220) [3]
H.H. indicator diagram (1822) | Clapeyron indicator diagram (1834) |
“The principles I have adopted lead to a theory of the steam-engine very different from the one generally received, but at the same time much more accordant with facts. It is the opinion of many philosophers that the mechanical power of the steam-engine arises simply from the passage of heat from a hot to a cold body, no heat being necessarily lost during the transfer. This view has been adopted by Clapeyron in a very able theoretical paper, of which there is a translation in the Third part of Taylor's Scientific Memoirs. This philosopher agrees with Carnot in referring the power to vis viva developed by the caloric contained by the vapor in its passage from the temperature of the boiler to that of the condenser. I conceive that this theory, however ingenious, is opposed to the recognized principles of philosophy, because it leads to the conclusion that vis viva may be destroyed by an improper disposition of the apparatus.”— James Joule (1844), “On the Changes of Temperature produced by the Rarefaction and Condensation of Air” (pg. 188)
“Carnot’s Theory of the Motive Power of Heat – Published in 1824 in a work entitled Réflexions sur la Puissance Motrice du Feu, by M. S. Carnot. Having never met with the original work, it is only through a paper by M. Clapeyron, on the same subject, published in the Journal de l’École Polytechnique, Vol. XIV, 1834, and translated in the first volume of Taylor’s Scientific Memoirs, that the Author has become acquainted with Carnot’s Theory.”— William Thomson (1848), “On an Absolute Thermometric Scale” [4]
“Dulong, in in his ‘Researches on the Specific Heats of Elastic Fluids’, established, by experiments, which are free from all objections, that equal volumes of all elastic fluids at a given temperature and pressure, compressed or expanded suddenly by a given fraction of their volumes, release or absorb the same absolute quantity of heat.”— Emile Clapeyron (1834), “Memoir on the Motive Power of Heat” (pg. 73)
“It has been known for a long time that heat can develop ‘motive power’ [work] and, conversely, that by means of ‘motive power’ [work] heat can be produced.”— Emile Clapeyron (1834), “Memoir on the Motive Power of Heat” (pg. 74); see: mechanical equivalent of heat