In thermodynamics, entropy models are any of various verbal, visual, heuristic, or statistical teaching models used to describe the 1865 quantity 'entropy', defined in various ways by German physicist Rudolf Clausius during the years 1850 to 1875. Some of the various oft-cited entropy models are as follows:
Model | Picture | Notes | |
Four element theory Aristotle | 350BC | | Denser elements tend to rise; lighter elements fall; earth is the heaviest element; fire the lightest. “For any two portions of fire, small or great, will exhibit the same ratio of solid to void; but the upward movement of the greater is quicker than that of the less.” |
Three principles Geber | 790 | Metals are formed of two elements: sulphur, ‘the stone which burns’, the principle of combustibility, and mercury, the principle of metallic properties. Salt gives solidity. | |
Sulphur combustion model Paracelsus | 1524 | ||
Terra pinguis model Johann Becher | 1699 | ||
Phlogiston model Georg Stahl | 1703 | ||
Caloric model Antoine Lavoisier (1789) | 1789 | ||
Re-establishment of equilibrium in the caloric Sadi Carnot | 1824 | A Lavoisier-base view that heat consisted of indestructible caloric particles and that a body returned to its original position (state) at the end of one heat cycle. | |
Transformation content Rudolf Clausius | 1850 | ||
Dissipation (law of dissipation) William Thomson | 1852 | ||
Disgregation Rudolf Clausius | 1862 | [3] | |
Entropy (melting ice) Rudolf Clausius | 1862 | [1] | |
1870 | “The second law of thermodynamics has the same degree of truth as the statement that if you throw a tumblerful into the sea, you cannot get the same tumblerful out again.”— James Maxwell (1870), “Letter to John Strutt”, Dec 6; the “moral” of his Maxwell’s demon argument [21] | ||
Velocity distribution model (H-theorem) Ludwig Boltzmann | 1872 | ||
Entropy of mixing Willard Gibbs | 1876 | Note: this could have been Gibbs' 1902 work; see: Gilbert Lewis' 1925 The Anatomy of Science (pg. 148). | |
Disorder Hermann Helmholtz | 1882 | ||
Ghostly quantity John Perry | 1899 | ||
S = k ln W Max Planck | 1901 | ||
Mixed-up-ness Willard Gibbs | 1903 | Note: ditto to previous note. | |
Elementary disorder Max Planck | 1906 | ||
Typing monkeys Emile Borel (1913) | 1913 | ||
Entropies of bodies Gilbert Lewis | 1923 | ||
Entropy (shuffling cards) Gilbert Lewis Arthur Eddington | 1925 | Seems to have been first described in Lewis' The Anatomy of Science (1925); then expanded be Eddington in his The Nature of the Physical World (1928). | |
Arrow of time Arthur Eddington | 1928 | ||
Entropy (information) Leo Szilard (1929) | 1929 | ||
Information theory Claude Shannon | 1948 | Note: this has nothing to do with thermodynamics; contrary to popular opinion; but rather is a mis-informed urban myth existing in ignorant science. | |
Unscrambled eggs (Broken eggs) Walter Albersheim? | 1955 | ||
Entropy (child’s playroom) Peter Landsberg | 1961 | ||
Energy dispersal Peter Atkins | 1984 | ||
(spreading out of energy) Frank Lambert | 1999 | Entropy ≠ Disorder | In a view of entropy as "energy spreading out"; a misinformed view promoted by American organic chemist Frank Lambert; based on a reading of one of William Thomson's articles. |