The thermodynamics work of Willard Gibbs have been said, e.g. by Wilhelm Ostwald (1892), Pierre Duhem (c.1905), Carlo Cercignani (1989), and Ingo Muller (2007), to contain "hidden treasures" of the the "greatest variety and importance", as Ostwald put it. |
“The material of the work is still of direct importance at the moment, and the interest in it is not historical. For only a small part of the almost immeasurable results which are contained and suggested here have as yet been realized. There are still hidden treasures of the greatest variety and importance here for the theoretical and most of all for the experimental worker.”
"Johannes van der Waals was the first to see its hidden power, to perceive the phase rule, among the algebraic formulas where Gibbs had to some extent hidden it.”
A 2011 Amazon.com listing (by Elliots Books, Northford, Connecticut) of the original "galley proof" of American engineer Willard Gibbs' 1876 On the Equilibrium of Heterogeneous Substances, selling for $50,000 dollars, the original copy Gibbs had to approve before the finial version was sent off to the printers. [8] The actuality of the selling price was verified by Libb Thims who contacted the seller. |
“Gibbs succinct and abstract style and unwillingness to include examples and applications to particular experimental situations made his work very difficult to read. Famous scientists such as Helmholtz and Planck developed their own thermodynamic methods in an independent fashion and remained quite unaware of the treasures buried in the third volume of Transactions of the Connecticut Academy of Arts and Sciences.”
“Ostwald, the German translator of Gibbs, had said that he undertook the task because he believed in hidden treasures in Gibbs’ work. He was right, and le Chatelier and later Haber and Bergius were chemists who uncovered and lifted the treasures as did Roozeboom.”
“How much of the work of Gibbs is still untapped—relations that may be of chemical and biochemical importance—we cannot tell. It is interesting to remember that Gibbs had formulated the principle of Donnan equilibrium in 1876 thirty five years before Donnan. Nobody recognized this until G.S. Adair one of the few biochemists who had actually read Gibbs, pointed it out in 1923. One wonders what other precious nuggets may still be hidden in this work.”— John Edsall (1974), “Some Notes and Queries on the Development of Bioenergetics” (pg. 104)