Summary the Lewis inequality for an unnatural process according to standard 1933 definition of English chemical thermodynamicist Edward Guggenheim. [1]
In inequalities, the Lewis inequality for an unnatural process is: [1]
for a differential change in the system, or:
for a change in the system on going from an initial state to a final state. The Lewis inequality for an "unnatural process", of the two types of Lewis inequalities, is inequality for a non-spontaneous process or reaction. The ‘type’ of systems here being closedisothermal-isobaric systems not harnessed in some way for the production of useful work, which include the common cases of reactions which ‘run freely’, like the combustion of a fuel, the action of an acid upon metal, or a reaction between two people on the surface of the earth. [1]
References 1. Guggenheim, Edward, A. (1933). Modern Thermodynamics by the Methods of Willard Gibbs (pg. 17). London: Methuen & Co. 2. Lewis, Gilbert N. and Randall, Merle. (1923). Thermodynamics and the Free Energy of Chemical Substances (pgs. 160-61). McGraw-Hill Book Co., Inc.
