“How can disequilibrium, order, and in particular free energy supplies that enable life to maintain its organization emerge form an apparent chaotic early universe in thermal and chemical equilibrium.”
Frautschi's entropy gap model: a "schematic dependence of entropy S and maximum (equilibrium) energy Smax in the expanding universe" (1988); such that the gap between to the two line, Smax - S, represent the room for order in the universe, and that this is how life emerged in the context of the second law. [1] |