A 1768 rendition of English physicist and chemist Robert Boyle’s circa 1660 bird in vacuum experiments, by English artist Joseph Wright, somewhat incorrectly entitled “An Experiment on a Bird in an Air Pump” (incorrect on the fact that the bird as depicted is in a vacuum bulb, and not in the air pump); a noted thermodynamics anecdote: the odd experiment done so to test and hence disprove English scientist Thomas Hobbes' "wind theory of cold". [13] |
See main: Animal in vacuum experimentFrequently, in reading up on the history of thermodynamics one will come across a mention of how in circa 1660s Irish scientist Robert Boyle put live animals inside a vacuum and then froze them. After coming across this trivia several times one begins to wonder what goaded Boyle into such a puzzling experiment?
English physicist James Joules' famous 1847 Niagara Falls honeymoon experiment, where he measured the mechanical equivalent of heat. |
See main: Niagara FallsJoule’s draw to experimentation, much of it done at the family brewery, was such that Joule rarely left home without scientific apparatus. Indeed, while visiting a waterfall with his wife on their honeymoon in 1847, he produced a thermometer with which to measure the change in the temperature of the water as it fell. [10]
A depiction of "mean free path", that of a newly-opened perfume bottle, from David Layzer's 1975 article "The Arrow of Time", which illustrates the famous Clausius-Ballot "dinning room anecdote" on the nature of the speed of gas particles and the velocity of the sent of hot food. [22] |
See main: Dinning room anecdoteIn German physicist Rudolf Clausius famous 1857 paper “On the Nature of the Motion which we call Heat”, he deduced the average speed of particles to be moving in the neighborhood of 300 to 1,000 meters per second (modern values often cite 500-meters per second or 1200-mph). This calculation drew a quick response from Dutch meteorologist Christoph Ballot who argued that if he were seated in a long dining room and the butler brought in dinner, it would be some moments before the smell of the food would reach his nose. [8] A response to this objection by Clausius resulted in the development of the concept of mean free path. [9]
One of Maxwell's thermodynamic surfaces, that he made in 1875 and sent to American engineer Willard Gibbs as a gift. |
“Copies of this model were distributed by Maxwell evidently with a certain amount of playful mystery, for each recipient thought that he was the happiest possessor of (at most) three. The writer knows of at six at least, and possibly there are more.”
“He came to Cambridge, and asked me if I could tell him of anyone who could make a good Professor of Molecular Physics.” Thomson told him that one of the greatest molecular physicists in the world was Willard Gibbs, and he livened in America. The president responded that Thomson probably meant Wolcott Gibbs, a Harvard chemist. Thomson was empathetic that he did mean Willard Gibbs, and tried to convince his visitor that Gibbs was indeed a great scientist. “He sat thinking for a minute or two”, Thomson continues, “and then said, “I’d like you to give me another name. Willard Gibbs can’t be a man of much personal magnetism or I should have heard of him.’”